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Fabrication and Employment of Organic thin films for Organic Light Emitting Diodes

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Abstract
Organic light emitting diodes based lighting technology is focus of significant academic research and industrial development interest, as they potentially offer unique advantages over their inorganic counterparts in terms of cost reductions, compatibility with low-temperature and printing-based manufacturing. Potential applications of organic light emitting devices span a broad range of products including displays, large area lighting, advertising, information, communication and bio-sensing devices. Although a great progress has been made in this area so far, still requires the search for alternative cost effective fabrication for the development of these low cost organic electronics devices is vital in order meet the demand of industrial large scale production. A wealth of solution processable materials has been synthesized that hold key advantages such as reduced production cost, compatibility with a vast range of substrates such as transparent glass and flexible polymeric materials, and also open new doors to explore alternative low cost fabrication methods.
In this thesis, fabrication methods of functional thin films of organic solution processable materials have been reported and also their deployment for organic light emitting diodes device fabrication from them. Thin films are deposited by electrospray deposition technique in a vacuum-free environment using solution processable materials' inks as precursors. The effects of electrospray process parameters on film's characteristics are described thoroughly. As a means of film characterization, morphology, elemental analysis, optical analysis and current density analysis for organic light emitting diode device applications are reported. The results obtained have showed that in terms of functionality, the thin films of solution processing materials are suitable to replace their vacuum processed analogues as building blocks in organic light emitting diodes devices. The work opens a fabrication route for a next generation organic electronics device which could lead to important advancement in electronics industry.
Author(s)
Maria Mustafa
Issued Date
2014
Awarded Date
2014. 2
Type
Dissertation
URI
http://dcoll.jejunu.ac.kr/jsp/common/DcLoOrgPer.jsp?sItemId=000000006600
Affiliation
제주대학교 대학원
Department
대학원 메카트로닉스공학과
Advisor
Kyung Hyun Choi
Table Of Contents
1 Introduction 1
1.1 Organic Light Emitting Device 2
1.2 Promising Materials for Organic Light Emitting Devices 6
1.3 Fabrication Processes 11
1.4 Electrospray Fabrication Technique 15
1.5 Research Motivation and Thesis Outline 18
2 Fabrication of Organic Thin Films 21
2.1 Poly [2-methoxy-5-(2'-ethylhexyloxy)-(p phenylenevinylene)] Thin Film 21
2.1.1 MEH-PPV Polymeric Thin Film Deposition 24
2.1.2 Thin Film Characterization 28
2.1.3 Conclusions 35
2.2 Poly[9,9-dioctylfluorenyl-2,7-diyl]-co-1,4-benzo-(2,1,3)-thiadiazoleThin Film 36
2.2.1 F8BT Polymeric Thin Film Deposition 39
2.2.2 Thin Film Characterization 43
2.2.3 Conclusions 51
2.3 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline Organic Thin Film 51
2.3.1 Small Molecule based BCP Organic Thin Film Deposition 54
2.3.2 Thin Film Characterization 59
2.3.3 Conclusions 63
3 Organic Light Emitting Devices Fabrication and Performance Evaluation using electrospray deposited Functional thin films 65
3.1 MEH-PPV Polymer based OLED 65
3.1.1 OLED Device Fabrication 65
3.1.2 OLED Device Performance 66
3.2 F8BT Polymer thin film based OLED 67
3.2.1 OLED Device Performance 67
3.2.2 OLED Device Performance 69
3.3 F8BT Polymer thin film based OLED with BCP as EIL 70
3.3.1 OLED Device Preparation 70
3.3.2 OLED Device Performance 70
3.4 Conclusions 74
4 Executive Summary 75
5 Future Work 79
References 80
Degree
Doctor
Publisher
제주대학교 대학원
Citation
Maria Mustafa. (2014). Fabrication and Employment of Organic thin films for Organic Light Emitting Diodes
Appears in Collections:
Faculty of Applied Energy System > Mechatronics Engineering
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