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제주지역 양돈 악취물질의 분석 및 발생 특성

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Abstract
In this study, the 9 designated odorous compounds have been analyzed from four swine farms in Jeju Island, in order to investigate the emission characteristics and odor contribution by different ventilation types.
The ammonia showed the highest concentration in the fattening room of winch-curtain ventilation type ("C-farm"), and the hydrogen sulfide concentration was high in the growing room of enclosed ventilation type. Not only the odorous sulfur compounds, i.e., DMS, and DMDS, but also the volatile fatty acids, i.e., PA, n-BA, and iso-VA showed high concentrations in the winchcurtain ventilation type swine farms. However, the concentrations of H2S and n-VA were high in the enclosed ventilation type swine farms. The odor quotient (OQ) of n-BA was the highest among the odorous com -pounds, whereby the odor contributions by volatile fatty acids were high in all swine farms. Consequently, the volatile fatty acids might be considered as
the major odor causing compounds to be controlled. In addition, the sum of odor quotient (SOQ) showed high values of growing room in "A-farm" (the enclosed ventilation type). On the comparison of the odor contribution, the volatile fatty acids were the highest in the range of 56.8~95.5% in all farms, followed by sulfur com -pounds and ammonia. Futhermore, the odor contribution of volatile fatty acids showed 72.4%, and it was 26.3% for sulfur compounds and 1.3% for ammonia in enclosed ventilation type. On the other hand, in winch-curtain ventilation type, the odor contribution of volatile fatty acids was higher as 91.1%, and it was relatively low as 7.7% for sulfur compounds and 1.2% for ammonia, resp -ectively.
Author(s)
정길원
Issued Date
2018
Awarded Date
2018. 8
Type
Dissertation
URI
http://dcoll.jejunu.ac.kr/common/orgView/000000008709
Alternative Author(s)
Jeong, Gil Won
Affiliation
제주대학교 일반대학원
Department
대학원 화학과
Table Of Contents
List of Tables ⅲ
List of Figures ⅳ
ABSTRACT ⅴ
I. 서 론 1
II. 연구방법 5
1. 시료 채취 및 기기
1.1 시료 채취5
1.2 측정기기 6
1.2.1 Low Volume Air Sampler 6
1.2.2 진공흡입상자6
1.2.3 UV-Visible Spectrophotometer 6
1.2.4 Gas chromatography 6
2. 악취물질 분석
2.1 암모니아 채취 및 분석 7
2.2 황화합물 채취 및 분석 8
2.3 휘발성 저급지방산 채취 및 분석10
2.4 분석 데이터 신뢰도 평가11
III. 결과 및 고찰13
1. 돈사 농장별 악취물질 농도
1.1 암모니아 농도 13
1.2 황화합물 19
1.2.1 황화수소 농도 20
1.2.2 메틸머캅탄 농도25
1.2.3 이황화메틸 농도29
1.2.4 이황화이메틸 농도33
1.3 휘발성 저급지방산 농도 34
1.3.1 프로피온산 농도35
1.3.2 n-뷰티르산 농도39
1.3.3 iso-발리르산 농도 43
1.3.4 n-발레르산 농도47
2. 악취 원인물질 기여도 52
Ⅳ. 결 론 58
Ⅴ. 참고문헌60
Degree
Master
Publisher
제주대학교 일반대학원
Citation
정길원. (2018). 제주지역 양돈 악취물질의 분석 및 발생 특성
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